Five pyrethroid pesticide residues for three kinds of traditional Chinese medicines using GC-MS

LIU Hongbo

doi:10.11833/j.issn.2095-0756.2015.01.016

Volume 32 Issue 1

Jan. 2015

Turn off MathJax

Article Contents

Article Navigation > Journal of Zhejiang A&F University > 2015 > 32(1): 110-115

LIU Hongbo. Five pyrethroid pesticide residues for three kinds of traditional Chinese medicines using GC-MS[J]. Journal of Zhejiang A&F University, 2015, 32(1): 110-115. doi: 10.11833/j.issn.2095-0756.2015.01.016

Citation:

LIU Hongbo. Five pyrethroid pesticide residues for three kinds of traditional Chinese medicines using GC-MS[J]. Journal of Zhejiang A&F University, 2015, 32(1): 110-115. doi: 10.11833/j.issn.2095-0756.2015.01.016

Five pyrethroid pesticide residues for three kinds of traditional Chinese medicines using GC-MS

doi: 10.11833/j.issn.2095-0756.2015.01.016

LIU Hongbo^,

1.
School of Forestry and Biotechnology, Zhejiang A & F University, Lin’an 311300, Zhejiang, China

Received Date: 2014-04-09
Rev Recd Date: 2014-09-04
Publish Date: 2015-02-20

Abstract

Methods for residual determination by gas chromatography mass spectrometry （GC-MS） of five pyrethroid pesticides in Chrysanthemum morifolium, Atractylodes macrocephala and Cornus officinalis were established. Cloud point extraction-back extraction was used as sample pretreatment method,and PEG 6000 was used as an extraction agent, isooctane was used as a back-extractant, a chromatographic column HP-5MS was used as an analytical column. Content was calculated by the external standard method using GC-MS. Results showed a linear range from 15.00 to 2 000.00 g kg－1 with favorable correlation coefficients （r=0.955－0.999）. For the five pyrethroid pesticides, the limit of detection was 0.63-3.10 gkg－1 and quantitation was 2.10－10.31 gkg－1. At spiked concentrations of 50.00-500.00 gkg－1, recoveries ranged from 71.22% to 91.00%. This proposed method can be applied to determine pyrethroid pesticide residues in Chrysanthemum morifolium, A. macrocephala, and Cornus officinalis. ［Ch, 4 fig. 4 tab. 19 ref.］
- Chrysanthemum morifolium,
- Atractylodes macrocephala,
- Cornus officinalis,
- pyrethoid pesticide,
- GC-MS,
- residue detection

Relative Article

[1]	WU Yuchen, LIN Fang, ZHANG Jiayang, ZHANG Lulu. Effects of single/mixed sowing of three medicinal plants on the contents of carbon, nitrogen and enzymes activities of sandy soil . Journal of Zhejiang A&F University, 2021, 38(2): 329-335. doi: 10.11833/j.issn.2095-0756.20200486
[2]	LIU Tingsong, WANG Hui, WANG Tongshu, JIANG Jun, WANG Jie, SUN Fangli, YANG Xianjin. Dimensional stability and mold resistance to bamboo treated in gaseous phase fluorination . Journal of Zhejiang A&F University, 2020, 37(2): 350-356. doi: 10.11833/j.issn.2095-0756.2020.02.021
[3]	LI Qiao, ZHANG Shaoyong, QIU Huikang, CHEN Ming, YE Yuzhu, YUAN Yuan. Field efficacy of six trunk-injected pesticides on Bursaphelenchus xylophilus . Journal of Zhejiang A&F University, 2016, 33(4): 718-723. doi: 10.11833/j.issn.2095-0756.2016.04.023
[4]	LIU Qing, TONG Senmiao, MA Jianyi. Volatile compounds from bamboo vinegar with HS-SPME and GC-MS . Journal of Zhejiang A&F University, 2014, 31(2): 308-314. doi: 10.11833/j.issn.2095-0756.2014.02.022
[5]	FAN Jianting, ZHANG Dongyong, ZHANG Zuping, MENG Junguo, WANG Yiping. Feeding behavior of Monochamus alternatus and its relationship with the host volatiles . Journal of Zhejiang A&F University, 2014, 31(1): 78-82. doi: 10.11833/j.issn.2095-0756.2014.01.012
[6]	TOU Peiming, SUN Shufang, ZHANG Xinfeng, SI Jinping, LIU Jingjing. Mineral elements in Chrysanthemum morifolium at different harvest stages . Journal of Zhejiang A&F University, 2013, 30(6): 858-862. doi: 10.11833/j.issn.2095-0756.2013.06.009
[7]	DU Ming-li, GAO Qun-ying, GAO Yan, ZHANG Ru-min. Organic compounds in exotic Coreopsis grandiflora using GC-MS . Journal of Zhejiang A&F University, 2012, 29(2): 313-318. doi: 10.11833/j.issn.2095-0756.2012.02.024
[8]	GUO Ming, WU Xiao-peng, SUN Dong-hai, ZHOU Jian-zhong, ZHANG Hua. A new matrix solid-phase for heavy metal ion extraction and residual testing . Journal of Zhejiang A&F University, 2012, 29(4): 551-557. doi: 10.11833/j.issn.2095-0756.2012.04.011
[9]	YU Wei-wu, FU Qing-gong, ZENG Yan-ru, TONG Zai-kang. Trait variances of Cornus officinalis fruit from Henan and Zhejiang major producing areas . Journal of Zhejiang A&F University, 2010, 27(5): 713-718. doi: 10.11833/j.issn.2095-0756.2010.05.012
[10]	YU Wei-wu, LI Zhang-ju, ZENG Yan-ru, DAI Wen-sheng. Measurement of main effective medicinal ingredients of elite cultivars of Cornus officinalis and their quality evaluation . Journal of Zhejiang A&F University, 2009, 26(2): 196-200.
[11]	CHU Kai-jiang, PAN Qiu-xiang, LI Lin, CHEN Bin-long, HE Fu-ji. A regional experiment of ‘Zheshu No.1’ and ‘Zheshu No.2’ cultivars of Atractylodes macrocephala in Zhejiang Province . Journal of Zhejiang A&F University, 2008, 25(1): 127-130.
[12]	HUANG You-jun, WANG Pei-jun, SHEN Tian-peng, XIA Guo-hua, HE Fu-ji, DAI Shi-wen, CHEN Quan-ming. Anatomical comparison for rhizomes of Atractylodes macrocephala with different origins . Journal of Zhejiang A&F University, 2008, 25(2): 153-157.
[13]	ZHAO Hong-bo, CHEN Fa-di, FANG Wei-min. Detection methods of pollen viability of Dendranthema . Journal of Zhejiang A&F University, 2006, 23(4): 406-409.
[14]	ZHOU Jian-zhong, LI Bing. Mass fraction of borneol in 4 traditional Chinese medicines measured by gas chromatography . Journal of Zhejiang A&F University, 2005, 22(3): 355-358.
[15]	HE Fu-ji, CHEN Bin-long, HE Hao-liang, FU Shun-hua, WANG Yi-feng. Genetic analysis of main traits and selection of superior provenances and superior individuals of Atractylodes macrocephala . Journal of Zhejiang A&F University, 2005, 22(5): 524-529.
[16]	LI Zhang-ju, QIAN Lian-fang, DAI Wen-sheng, WANG Zu-tang, LUO Wen-jian, XU Shu-hong, YU Wei-wu. Selection and breeding of superior clones of Cornus officinalis . Journal of Zhejiang A&F University, 2003, 20(4): 331-335.
[17]	LIU Xing-quan, XU Lu. Three-dimensional quantitative structure-activity relationships between structure of pyrethroid and their acute toxicity . Journal of Zhejiang A&F University, 2002, 19(4): 337-341.
[18]	WU Li-dong, LIAO Li-hong, HUA Wen-li, MAO Jun-hua, HU Jin-gen. Analysis of methamidophos residual dose absorbed in bamboo leaves . Journal of Zhejiang A&F University, 2000, 17(2): 232-233.
[19]	Fu Shenyuan, Li Zhangju, Wang Zutan. Study on the Gross Saponins in Natural Beverage of Cornus officinalis. . Journal of Zhejiang A&F University, 1998, 15(1): 105-107.
[20]	Fu Shenyuan, Chen Lijiang, Ge Shenjin. Effect of Cornus of ficinalis Stone Extracts on Mildew Resistant Stability of Starch Adhesive. . Journal of Zhejiang A&F University, 1997, 14(4): 406-409.

References
Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Get Citation

PDF

XML

Article views(3258) PDF downloads(597) Cited by()

Proportional views

Five pyrethroid pesticide residues for three kinds of traditional Chinese medicines using GC-MS

1. School of Forestry and Biotechnology, Zhejiang A & F University, Lin’an 311300, Zhejiang, China

Received Date: 2014-04-09

Rev Recd Date: 2014-09-04

Publish Date: 2015-02-20

Key words:

Abstract: Methods for residual determination by gas chromatography mass spectrometry （GC-MS） of five pyrethroid pesticides in Chrysanthemum morifolium, Atractylodes macrocephala and Cornus officinalis were established. Cloud point extraction-back extraction was used as sample pretreatment method,and PEG 6000 was used as an extraction agent, isooctane was used as a back-extractant, a chromatographic column HP-5MS was used as an analytical column. Content was calculated by the external standard method using GC-MS. Results showed a linear range from 15.00 to 2 000.00 g kg－1 with favorable correlation coefficients （r=0.955－0.999）. For the five pyrethroid pesticides, the limit of detection was 0.63-3.10 gkg－1 and quantitation was 2.10－10.31 gkg－1. At spiked concentrations of 50.00-500.00 gkg－1, recoveries ranged from 71.22% to 91.00%. This proposed method can be applied to determine pyrethroid pesticide residues in Chrysanthemum morifolium, A. macrocephala, and Cornus officinalis. ［Ch, 4 fig. 4 tab. 19 ref.］

Five pyrethroid pesticide residues for three kinds of traditional Chinese medicines using GC-MS

doi: 10.11833/j.issn.2095-0756.2015.01.016

Abstract

References

Proportional views

通讯作者: 陈斌, bchen63@163.com

Related

Proportional views