Synthesis, characterization and property of hydroxyethyl cellulose trimethylsilylated derivatives

GUO Ming; WANG Peng; LI Ming-hui; YANG Jun; WANG Chun-peng; CHU Fu-xiang

Volume 25 Issue 1

Jun. 2018

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GUO Ming, WANG Peng, LI Ming-hui, YANG Jun, WANG Chun-peng, CHU Fu-xiang. Synthesis, characterization and property of hydroxyethyl cellulose trimethylsilylated derivatives[J]. Journal of Zhejiang A&F University, 2008, 25(1): 1-6.

Citation:

GUO Ming, WANG Peng, LI Ming-hui, YANG Jun, WANG Chun-peng, CHU Fu-xiang. Synthesis, characterization and property of hydroxyethyl cellulose trimethylsilylated derivatives[J]. Journal of Zhejiang A&F University, 2008, 25(1): 1-6.

Synthesis, characterization and property of hydroxyethyl cellulose trimethylsilylated derivatives

1.
School of Sciences, Zhejiang Forestry College, Lin'an 311300, Zhejiang, China;
2.
Institute of Chemical Industry of Forest Products, the Chinese Academy of Forestry, Nanjing 210042, Jiangsu, China

Received Date: 2007-04-14
Rev Recd Date: 2007-07-23
Publish Date: 2008-02-10

Abstract

Water miscible hydroxyethyl cellulose(HEC) was modified to increase its fat-solubility by reacting with hexamethyldisilazan. Its synthetic product is trimethylsilyl hydroxyethyl cellulose(TMSHEC). The structure and the surface feature of TMSHEC were characterized by infrared spectra(IR) and scanning election microscope(SEM), the properties were investigated by thermogravimetic analysis(TGA), differential scanning calorimetry(DSC) and mould degradation. The results of TGA and DSC show that the thermal stability and fat-solubility of trimethylsilyl modification cellulose gives rise to a clear improvement. And the mould degradation preliminary experiment proves that the TMSHEC can be biodegraded.
- chemistry of forest products,
- hydroxyethyl cellulose,
- hexamethyldisilazan,
- infrared spectra,
- scanning election microscope,
- thermal analysis

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis, characterization and property of hydroxyethyl cellulose trimethylsilylated derivatives

1. School of Sciences, Zhejiang Forestry College, Lin'an 311300, Zhejiang, China;

2. Institute of Chemical Industry of Forest Products, the Chinese Academy of Forestry, Nanjing 210042, Jiangsu, China

Received Date: 2007-04-14

Rev Recd Date: 2007-07-23

Publish Date: 2008-02-10

Key words:

Abstract: Water miscible hydroxyethyl cellulose(HEC) was modified to increase its fat-solubility by reacting with hexamethyldisilazan. Its synthetic product is trimethylsilyl hydroxyethyl cellulose(TMSHEC). The structure and the surface feature of TMSHEC were characterized by infrared spectra(IR) and scanning election microscope(SEM), the properties were investigated by thermogravimetic analysis(TGA), differential scanning calorimetry(DSC) and mould degradation. The results of TGA and DSC show that the thermal stability and fat-solubility of trimethylsilyl modification cellulose gives rise to a clear improvement. And the mould degradation preliminary experiment proves that the TMSHEC can be biodegraded.

Synthesis, characterization and property of hydroxyethyl cellulose trimethylsilylated derivatives

Abstract

References

Proportional views

通讯作者: 陈斌, bchen63@163.com

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